کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1300975 1498744 2014 15 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Zinc hydroxides and oxides supported by organic ligands: Synthesis and structural diversity
ترجمه فارسی عنوان
هیدروکسید های روی و اکسید ها توسط لیگاندهای آلی پشتیبانی می شوند: سنتز و تنوع ساختاری
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• Zinc hydroxides and oxides derived from organozinc complexes.
• The preparation and structural variety of organozinc hydroxides.
• Synthetic methods and structural types of zinc oxide clusters.
• The relevance of zinc hydroxides and oxides to functional materials.

This review focuses on the synthesis, reactivity and structural chemistry of zinc hydroxides and oxides derived essentially from organozinc compounds. It demonstrates the advantages of the organometallic route to these classes of compounds that is time and atom efficient. We have surveyed the preparation of organozinc hydroxide complexes via direct hydrolysis of both R2Zn compounds and alkylzinc complexes of the type RZn(L) (where L = monoanionic, mono- or multidentate organic ligand). The variety of their molecular structures is discussed with an emphasis on how the character of zinc bonded alkyl substituents or L ligands can influence the stability and the mode of aggregation of the resulting zinc hydroxides. The section dedicated to synthetic procedures and the solid state structures of zinc oxides focuses on the following aspects: (i) zincoxane compounds; (ii) the encapsulation of ZnO species into organozinc moieties and (iii) zinc oxide complexes supported by organic ligands. Finally, utility of oxozinc carboxylates as a predesigned molecular platform for modelling of the reactivity of prototypical Zn-MOFs towards H2O and donor solvents is presented.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volumes 270–271, July 2014, Pages 112–126
نویسندگان
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