کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301150 1498794 2010 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Construction of M–M bonds in late transition metal complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Construction of M–M bonds in late transition metal complexes
چکیده انگلیسی

The 16-electron Co, Rh and Ir half-sandwich complexes of Cp#M[E2C2(B10H10)] and Cp#M(E2S2C6H4) (M = Co, Rh, Ir, Ru; E = S, Se) containing chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligands and benzenedithiolato ligands are promising precursors to build multimetallic clusters by reactions with low oxidation state late transition metal reagents. Such reactions lead to successful constructions of M–M bonds between iridium, rhodium, cobalt, ruthenium, and other late transition metals. Most of these complexes have been characterized by X-ray single crystal determinations and some have been studied by computational methods. Such theoretical studies reveal the covalent bonding nature of those multinuclear complexes. Some of these clusters have been found to have interesting nonlinear optical properties.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 254, Issues 11–12, June 2010, Pages 1260–1272
نویسندگان
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