کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1301185 | 1498796 | 2010 | 26 صفحه PDF | دانلود رایگان |
Current attention continues to revolve around the chemistry and biochemistry associated with polyphosphate anions because of their importance in biology. A pivotal intermediate within this family is the pyrophosphate tetraanion, P2O74−. Considering its biological relevance and the multidentate nature that makes it an ideal ligand in the field of the coordination chemistry, there is a growing interest in the use of this anion in building new class of molecules/compounds for different purposes. While the total number of characterized structures still remains modest, several new pyrophosphate-containing coordination complexes have been reported in the last decade, as well as different solid-state structures. This review focuses on the structural, magnetic, and biological properties of coordination complexes incorporating the pyrophosphate ligand reported to date.
Journal: Coordination Chemistry Reviews - Volume 254, Issues 7–8, April 2010, Pages 890–915