کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301218 | 1498815 | 2008 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Transition metal-dialkyl compounds (LxMR2; R = alkyl; M = metals of groups VI–X)—Synthesis, structure, reactivity and applications
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This review deals with the synthesis, properties and applications of dialkyl complexes of the type LxMR2 (R = alkyl; Lx = ligands; M = transition metals of groups VI to X. Discussion on the comparison with analogous monoalkyl-metal complexes is also carried out. Possible reactivity patterns include: insertions of small molecules into the metal and carbon σ-bond, cyclometalations, oxidative addition, transmetalation, and thermal decomposition; these are discussed. The influence of various factors on the stability and reactivity of these title compounds is described. The applications and intermediacy of transition metal-dialkyl species in various catalytic reactions are highlighted.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 252, Issues 15–17, August 2008, Pages 1668–1688
Journal: Coordination Chemistry Reviews - Volume 252, Issues 15–17, August 2008, Pages 1668–1688
نویسندگان
Emma Hager, Akella Sivaramakrishna, Hadley S. Clayton, Mokgolela M. Mogorosi, John R. Moss,