کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301340 1498829 2007 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding
چکیده انگلیسی

The latest advances in N-heterocyclic carbene-based organometallic chemistry have drawn increasing attention to this class of ancillary ligands as an attractive alternative to tertiary phosphines. Studies focusing on the fundamental steric and electronic factors characterizing this family of compounds are therefore essential for the rationalization of the activity observed for such organometallic complexes in metal-mediated organic transformations. This knowledge is also of fundamental importance in catalyst design efforts. This review intends to provide a comprehensive overview of the progress in this area.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 251, Issues 5–6, March 2007, Pages 874–883
نویسندگان
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