کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306892 | 975109 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Anions as stabilizing ligands for Ni(III)(cyclam) in aqueous solutions
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
Several new anions were shown to be good stabilizing ligands for Ni(III)L(H2O)23+, (L = 1,4,8,11-tetraazacyclotetradecane, cyclam) in aqueous solutions. Mo7O246-, phosphonates, phosphates, including the biological relevant ATP were shown to have the highest binding constants to the tervalent nickel ion. The results suggest that the charge density of the anion at the binding site and the basicity of the anion are the main factors affecting the binding constant to the central Ni(III) cation.
The stability constants K = [Ni(III)LX23-2n]/[Ni(III)L(H2O)23+][Xn-]2 increase with the n and with the basicity of Xn−.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 363, Issue 12, 15 October 2010, Pages 2819–2823
Journal: Inorganica Chimica Acta - Volume 363, Issue 12, 15 October 2010, Pages 2819–2823
نویسندگان
Dror Shamir, Israel Zilbermann, Eric Maimon, Alexander I. Shames, Haim Cohen, Dan Meyerstein,