کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306897 | 975109 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization, spectroscopy, electronic and redox properties of a new nickel dithiolene system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new dithiolene ligand with 3,5-dibromo substituted phenyl groups was designed and synthesized. The protected form of the ligand was reacted with a nickel salt providing neutral Ni(S2C2(3,5-C6H3Br2)2)2 and anionic [Ni(S2C2(3,5-C6H3Br2)2)2]− isolated as a Bu4N+ salt. Both were characterized by UV–Vis and IR spectroscopy and compared with the similar known molecular systems. They exhibit intense low energy transitions that are characteristic of such systems. The electrochemical behavior of these molecules was investigated by cyclic voltammetry.
A new Ni-dithiolene system has been synthesized and characterized. Its redox and optical properties have been compared with known complexes.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 363, Issue 12, 15 October 2010, Pages 2857–2864
Journal: Inorganica Chimica Acta - Volume 363, Issue 12, 15 October 2010, Pages 2857–2864
نویسندگان
Partha Basu, Archana Nigam, Benjamin Mogesa, Suzanne Denti, Victor N. Nemykin,