کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1307106 1499187 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
First example of a 1:1 vanadium(IV)–citrate complex featuring the 2,2′-bipyridine co-ligand: Synthesis, X-ray crystal structure and DFT calculations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
First example of a 1:1 vanadium(IV)–citrate complex featuring the 2,2′-bipyridine co-ligand: Synthesis, X-ray crystal structure and DFT calculations
چکیده انگلیسی

An unprecedented 1:1:1 complex [VO(bipy)(cit[H]H)]·1.5H2O was obtained from the reaction of vanadium(III) chloride, 2,2′-bipyridine (bipy), and citric acid (cit[H]H3) in methyl alcohol/water. The citrate anion (cit[H]H)2− chelates the metal centre as a tridentate ligand via the unusually protonated α-alcoholic group, and two oxygen atoms from the α- and one β-carboxylate groups, the other β-carboxylic acid group remaining uncoordinated. A pseudo-octahedral coordination sphere is completed by a bidentate bipy unit. The electronic nature of this complex is investigated by means of DFT calculations.

An unprecedented complex [VO(bipy)(cit[H]H)]·1.5H2O was obtained from the reaction of vanadium(III) chloride, 2,2′ bipyridine (bipy), and citric acid (cit[H]H3) in methanol/water, and structurally characterised. The electronic nature of this complex was investigated via DFT calculations.Figure optionsDownload as PowerPoint slideHighlights
► An unprecedented 1:1:1 complex [VO(bipy)(cit[H]H)]·1.5H2O is reported.
► The citrate anion and bipyridine ligands chelate the metal centres in a monomeric complex.
► The electronic nature of the complex has been investigated via DFT calculations.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 400, 1 May 2013, Pages 107–114
نویسندگان
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