کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1307149 | 975124 | 2009 | 5 صفحه PDF | دانلود رایگان |
The hydrolysis of 4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid (DPPDA) esters is induced by lanthanide(III) ions. As the related 2,6-pyridinedicarboxylic acid esters are not cleaved, the effect is traced back on improved complexation of the lanthanides by the DPPDA esters. Time-resolved fluorescence spectroscopic and electrospray mass spectrometric investigations on the esters provide information on the progress of the reactions.
The hydrolysis of 4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid (DPPDA) esters is induced by lanthanide(III) ions. Time-resolved fluorescence spectroscopic and electrospray mass spectrometric investigations on the esters provide information on the progress of the reactions.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 362, Issue 2, 20 January 2009, Pages 421–425