Enantiopure platinum(II) complexes with chiral diphosphine and diphosphinite ligands derived from 2,2-biphosphole: Synthesis, crystal structure and catalysis

Chiral stereodynamic diphosphine and diphosphinite ligands derived from 2,2-biphospholes were used to form diastereo- and enantiopure platinum complexes through a metal kinetic dynamic resolution. Catalytic performances of these platinum complexes have been explored in asymmetric hydroformylation.