کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1307599 975147 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reaction of a bulky phosphite with [Ru3(CO)12]: The molecular structure of one of the decomposition products
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Reaction of a bulky phosphite with [Ru3(CO)12]: The molecular structure of one of the decomposition products
چکیده انگلیسی

Mono- and bis-substituted phosphite complexes [Ru3(CO)12−x Lx] (L = tris(2,4-di-tert-butylphenyl) phosphite; x = 1, 2) were synthesized by simple substitution reactions, and were characterized by spectroscopic methods. The monosubstituted ruthenium complex disproportionates in acetone producing a mononuclear ruthenium complex as one of the decomposition products. Single crystal X-ray diffraction analysis established the molecular structure of this new compound.

An interesting C–H activation is observed in one of the decomposition products obtained from the phosphite substituted ruthenium compound, [Ru3(CO)11L] (L = tris(2,4-di-tert-butylphenyl) phosphite). Mono- and bis-phosphite substituted complexes of trirutheniumdodecacarbonyl are synthesized by simple substitution reactions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 361, Issue 1, 1 January 2008, Pages 335–340
نویسندگان
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