کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308063 975162 2006 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and pH-sensitive luminescence of bis-terpyridyl iridium(III) complexes incorporating pendent pyridyl groups
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and pH-sensitive luminescence of bis-terpyridyl iridium(III) complexes incorporating pendent pyridyl groups
چکیده انگلیسی

A series of iridium(III) bis-terpyridine complexes have been prepared which incorporate pendent pyridyl groups at the 4′-positions of one or both of the terpyridine (tpy) ligands. These include: three mutually isomeric homoleptic complexes, in which the nitrogen atom of the pendent pyridyl is para, meta or ortho to the C–C bond to the terpyridine; their heteroleptic analogues in which the second ligand is 4′-tolyl-terpyridine (ttpy); analogous complexes of the new ligand, 4′-(2,6-dimethylpyrid-4-yl)-terpyridine; and related complexes incorporating an additional phenyl ring interposed between the terpyridine and the pendent pyridyl group. All of the complexes are luminescent in air-equilibrated aqueous solution at room temperature. The homoleptic complexes display structured emission resembling that of unsubstituted [Ir(tpy)2]3+, with luminescence lifetimes of around 1 μs under these conditions. The heteroleptic analogues give broader, red-shifted emission spectra, similar to that of [Ir(ttpy)2]3+, indicating that emission in these complexes arises primarily from a lower-energy excited state associated with the 4′-tolyl-terpyridine ligand. A further red-shift for the complexes incorporating the additional phenyl ring suggests that the emissive state involves the more conjugated phenylpyridyl-appended ligand in these cases. The luminescence of all of the heteroleptic complexes investigated, except the meta-substituted system, is sensitive to the protonation state of the pendent pyridyl group, and the structure of the ligand can have a significant influence on both the magnitude of the response and the pH region over which it occurs.

Three new series of pyridyl-appended bis-terpyridyl iridium complexes have been prepared. All of the complexes are luminescent at room temperature, with long luminescence lifetimes in the microsecond range in air-equilibrated aqueous solution. The emission intensity and lifetimes are sensitive to the protonation state of the pyridyl group, and emission may be either quenched or augmented according to the structure of the ligand.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 4, 1 March 2006, Pages 1222–1232
نویسندگان
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