Solution-mediated syntheses and characterizations of two new zincophosphites [C6H14N2]0.5[Zn(H2PO3)2] and [C4H12N2]0.5[(CH3)2NH2][Zn2(HPO3)3]

Compound 1 and 2 were solvothermally synthesized in the mixed solvents system. Compound 1 exhibits a neutral inorganic chain with hydrogen-bonded helix. Compound 2 presents a layer structure with 12-MRs.