کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1308403 | 975172 | 2005 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A gas-phase study of the gold-catalyzed coupling of alkynes and alcohols A gas-phase study of the gold-catalyzed coupling of alkynes and alcohols](/preview/png/1308403.png)
Mass spectrometric methods are used for an investigation of the C–O bond formation between alkynes and alcohols mediated by cationic gold(I) complexes. In the condensed-phase catalysis, an efficient coupling to the corresponding enol ethers has been observed. In the gas phase, however, kinetic and entropic restrictions are too large for both bare Au+ as well as (CH3)3PAu+ to permit bond formation in strictly bimolecular collisions occurring at thermal energies. The experimental findings are complemented by a theoretical study of the Au+/C2H2/CH3OH system using density functional theory.
Mass spectrometric methods are used for an investigation of the C–O bond formation between alkynes and alcohols mediated by cationic gold(I) complexes. In the condensed-phase catalysis, an efficient coupling to the corresponding enol ethers has been observed. In the gas phase, however, kinetic and entropic restrictions are too large for both bare Au+ as well as (CH3)3PAu+ to permit bond formation in strictly bimolecular collisions occurring at thermal energies. The experimental findings are complemented by a theoretical study of the Au+/C2H2/CH3OH system using density functional theory.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 358, Issue 14, 15 November 2005, Pages 4287–4292