کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308513 975174 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate
چکیده انگلیسی

The first organic amine templated 1-D holmium sulfate [C6N4H22]1.5[Ho2(SO4)6 · H2O] 1 has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA and ICP. The structure of framework compound 1 is constructed from the [–Ho–O–S–O–]n chains. Two types of [–Ho–O–S–O–]n   chains connect each other by sharing the bridging SO42- groups to generate a Ho–O–S ladder, while the adjacent ladders are connected by μ3-O atoms to form a novel triple ladders. The fully protonated triethylenetetraamine molecules are situated between the ladders, and involved in the hydrogen bonding with oxygen atoms of inorganic framework.

The first organic amine templated 1-D holmium sulfate [C6N4H22]1.5[Ho2(SO4)6 · H2O] (1) is constructed from the [–Ho–O–S–O–]n chains. Two types of [–Ho–O–S–O–]n chains connect each other by sharing the bridging SO42− groups to generate a Ho–O–S ladder, while the adjacent ladders are connected by μ3-O atoms to form a novel triple ladders.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 362, Issue 9, 1 July 2009, Pages 3299–3302
نویسندگان
, , , , , ,