Two metal–organic frameworks (MOFs) based on binuclear and tetranuclear units: Structures, magnetism and photoluminescence

Two new MOFs, [Mn(HBTC)(2-PyBim)(H2O)] (1) and [Zn2(BTC)(OH)(2-PyBim)] (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, 2-PyBim = 2-(2-pyridyl)benzimidazole), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction (XRD), infrared spectroscopy (IR), elemental analysis (EA). In 1, adjacent two Mn(II) ions are connected into binuclear Mn2 units which are bridged by HBTC2− anions to generate a two-dimensional (2D) (4,4) network. In 2, the Zn(II) ions are connected into tetranuclear Zn4 units which are bridged by the BTC3− anions to generate a 2D (3,6)-connected non-interpenetrating CdI2-type network with (43)2(46 · 66 · 83) topology symbol. Both 1 and 2 are extended into 3D supramolecular structure by hydrogen bonds and π⋯π interactions. Magnetic studies of 1 indicate that it exhibits ferromagnetic coupling between the binuclear Mn(II) ions, polymer 2 was found to exhibit photoluminescence at about 437 nm (λex = 365 nm).

Syntheses and characterizations of two novel metal–organic frameworks based on binuclear and tetranuclear units are described. 1 and 2 display 2D (4,4) network and (3,6)-connected network, respectively. The magnetic and photoluminescent properties have also been reported.Figure optionsDownload as PowerPoint slideHighlights
► Two novel 2D metal–organic frameworks with different topology have been synthesized and structurally characterized.
► 1 Consists of binuclear Mn2 units and displays ferromagnetic behavior.
► 2 Consists of tetranuclear Zn4 units and displays intense photoluminescent emission in the solid state.