Pt(II) compounds with sulfoxide ligands and crystal structures of complexes of the types I(R2SO)Pt(μ-I)2Pt(R2SO)I and trans-Pt(R2SO)(L)X2 (L = amine, pyridine and pyrimidine)

The crystal structures of two Pt(II) complexes of the type I(R2SO)Pt(μ-I)2Pt(R2SO)I were determined. The compounds are the trans isomers. Four mixed-ligands complexes trans-Pt(DMSO)(L)X2, where L = CH3NH2, t-BuNH2, pyridine, pyrimidine and X = Cl or I, were also studied by X-ray diffraction methods.