کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1309272 1499164 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Metal-mediated cyanamide–hydroxyguanidine coupling
ترجمه فارسی عنوان
اتصال متقابل هیدروکسی گویانیدین توسط سیانامین
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• First example of reaction between any nitrile group and any hydroxyguanidine.
• Zinc(II)-mediated coupling.
• Addition to metal-activated nitriles.
• Complexes are relevant to intermediates of the Zn(II)-catalyzed hydration of RCN.

Reaction of the cyanamides R2NCN (R = Me 2a, Et 2b) with the hydroxyguanidine OC4H8NC(NOH)NH2 (1) in the presence of zinc halides leads to [ZnX2{HNC(NR2)ONC(NH2)NC4H8O}] derived from the ZnII-mediated cyanamide–hydroxyguanidine coupling. This reaction is the first observation of interplay between any nitrile group and any hydroxyguanidine both in metal-involving and metal-free chemistry. Complexes 3a,b–5a,b rather rapidly degrade in solutions at RT, but solvates 3a,b·MeOH and 4a·MeOH are sufficiently stable in the solid state and they were characterized by IR, HRESI+-MS, solid state CP-MAS TOSS 13C NMR, and X-ray crystallography (for 3a,b). Complexes 4b and 5a,b were identified in solutions by HRESI+-MS.

The ZnII-mediated cyanamide–hydroxyguanidine coupling represents the first observation of interplay between any nitrile group and any hydroxyguanidine.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 425, 30 January 2015, Pages 114–117
نویسندگان
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