کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1309830 975223 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The lanthanide-containing cyclohexane-tri-carboxylate coordination polymers re-investigated
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The lanthanide-containing cyclohexane-tri-carboxylate coordination polymers re-investigated
چکیده انگلیسی

Reaction in water between trivalent lanthanide ions and ctc3− ligand leads to [Ln(ctc)(H2O)2 · 2.5H2O]∞ 3-D molecular networks with Ln = Tb–Yb or Y. These compounds look like molecular precursors for porous solids. Unfortunately, the dehydrated phases are not structurally characterized. We report here the study of the partially dehydrated phases with general formula [Ln(ctc)(H2O)2]∞ with Ln = Tb–Yb or Y obtained by freeze-drying of the corresponding hydrated phases. Their porosity is estimated as well as the luminescent properties of the Tb-containing compound.

We report here the study of the partially dehydrated phases with general formula [Ln(ctc)(H2O)2]∞ with Ln = Tb–Yb or Y obtained by freeze-drying of the corresponding hydrated phases. Their porosity is estimated as well as the luminescent properties of the Tb-containing compound.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 362, Issue 7, 15 May 2009, Pages 2123–2126
نویسندگان
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