کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1310120 975233 2008 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Metalloporphyrin catalyzed oxidation of methyl yellow and related azo compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Metalloporphyrin catalyzed oxidation of methyl yellow and related azo compounds
چکیده انگلیسی

Fe(TDCPP)Cl catalyzes the oxidation of simple azo compounds including 4-phenylazoaniline, 4-(phenylazo)-N-methylaniline and 4-(phenylazo)-N,N-dimethylaniline (methyl yellow). Methyl yellow and 4-(phenylazo)-N-methylaniline are N-demethylated to form 4-phenylazoaniline prior to further oxidation. Oxidation of 4-phenylazoaniline generates a variety of products as a result of multiple reaction pathways occurring simultaneously. One pathway for the oxidation of 4-phenylazoaniline involves oxidative cleavage of the azo linkage while additional pathways result in modification of 4-phenylazoaniline without cleavage of the azo linkage. One of these additional reaction pathways includes the formation of an additional azo linkage to yield 1,4′-bis(phenylazo)azobenzene.

Metalloporphyrin catalyzed oxidation of the azo dye methyl yellow is a complicated process. The initial N-dealkylation reactions produce 4-phenylazoaniline which is further oxidized. Oxidative decolorization of 4-phenylazoaniline involves both asymmetric cleavage of the azo linkage and oxidation of the amine group.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 361, Issue 8, 2 June 2008, Pages 2243–2251
نویسندگان
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