Formation of unusual ruthenium(III) carbonyl complex through ONS tricoordination of salicylaldehyde-N-phenylthiosemicarbazone

An unusual coordination mode of salicylaldehyde-N-phenylthiosemicarbazone (H2-Sal-Ptsc) ligand was observed in unusual ruthenium(III) carbonyl complex for the first time when it was reacted with [RuHCl(CO)(PPh3)3]. The EPR and electrochemical analysis conformed the formation of Ru(III) species.

An unusual coordination mode of salicylaldehyde-N-phenylthiosemicarbazone (H2-Sal-Ptsc) ligand was observed in unusual ruthenium(III) carbonyl complex for the first time.Figure optionsDownload as PowerPoint slide