کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1311095 | 975279 | 2011 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Design, synthesis and reactivity with dichloro-bis(triphenylphosphine) platinum(II) of two triazenide compounds Design, synthesis and reactivity with dichloro-bis(triphenylphosphine) platinum(II) of two triazenide compounds](/preview/png/1311095.png)
In the presence of sodium nitrite, the reaction of methyl anthranilate and 2-aminopyridine or o-aminobenzoic acid gives two triazenes, 1-[(2-carboxymethyl)benzene]-3-[2-pyridine]triazene (HL) and 1-[(2-carboxymethyl)benzene]-3-[o-aminobenzoic acid]triazene (H2L′), respectively. In the presence of Et3N, the reaction of Pt(PPh3)2Cl2 and HL or H2L′ produces two triazenido platinum(II) complexes, Pt(PPh3)2(L)Cl (1) and Pt(PPh3)2(L′) (2), respectively, which have been characterized by X-ray crystallography, 31P NMR spectra, UV–Vis spectra, emission spectra and cyclic voltammetry. When excited at 310 nm, complexes 1 and 2 show luminescence at 432 and 442 nm, respectively, which is consistent with the trend of the lowest-energy absorption wavelengths of 1 (376 nm) and 2 (379 nm). Complexes 1 and 2 exhibit one or two redox waves and follow the order 1 (0.97 V) → 2 (0.89 and 0.07 V), which is also in accordance with the trend of the lowest-energy absorption spectra of 1 (376 nm) and 2 (379 nm).
In the presence of Et3N, the reaction of Pt(PPh3)2Cl2 and 1-[(2-carboxymethyl)benzene]-3-[2-pyridine]triazene (HL) or 1-[(2-carboxymethyl)benzene]-3-[o-aminobenzoic acid]triazene (H2L′) produces two triazenido platinum(II) complexes, Pt(PPh3)2(L)Cl (1) and Pt(PPh3)2(L′) (2), respectively, which are characterized by X-ray crystallography, 31P NMR spectra, UV–Vis spectra, emission spectra and cyclic voltammetry. When excited at 310 nm, complexes 1 and 2 show luminescence at 432 and 442 nm, respectively, which is consistent with the trend of the lowest-energy absorption wavelengths of 1 (376 nm) and 2 (379 nm). Complexes 1 and 2 exhibit one or two redox waves and follow the order 1 (0.97 V) → 2 (0.89 and 0.07 V), which is also in accordance with the trend of the lowest-energy absorption spectra of 1 (376 nm) and 2 (379 nm).Figure optionsDownload as PowerPoint slideHighlights
► Our interests focused on design, synthesis and reactivity of new triazenide ligands.
► 1-[(2-carboxymethyl)benzene]-3-[2-pyridine]triazene (HL) was synthesized.
► 1-[(2-carboxymethyl) benzene]-3-[o-aminobenzoic acid]triazene (H2L’) was synthesized.
► Reaction of Pt(PPh3)2Cl2 and HL or H2L’ gave Pt(PPh3)2(L)Cl and Pt(PPh3)2(L’), respectively.
Journal: Inorganica Chimica Acta - Volume 373, Issue 1, 15 July 2011, Pages 276–281