کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311326 | 975310 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate The composition and structure of lithium tetrakis(pentafluorophenyl)borate diethyletherate](/preview/png/1311326.png)
چکیده انگلیسی
Treatment of LiC6F5 with B(C6F5)3 in equal volumes of light petroleum and diethyl ether at low temperature followed by slow warming to room temperature precipitates a microcrystalline solid which dries under vacuum to a material with the composition [Li(OEt2)3][B(C6F5)4]. Crystallization from diethyl ether yields solvent dependent [Li(OEt2)4][B(C6F5)4], which has been crystallographically characterised.
Treatment of LiC6F5 with B(C6F5)3 in light petroleum and diethyl ether at low temperature followed by crystallization yields solvent dependent [Li(OEt2)4][B(C6F5)4] which is readily converted to a material with the composition [Li(OEt2)3][B(C6F5)4].Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 363, Issue 1, 4 January 2010, Pages 275–278
Journal: Inorganica Chimica Acta - Volume 363, Issue 1, 4 January 2010, Pages 275–278
نویسندگان
Eddy Martin, David L. Hughes, Simon J. Lancaster,