کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311344 | 975315 | 2009 | 5 صفحه PDF | دانلود رایگان |
Treatment of [Bun4N][Ru(N)Cl4] with Na(OR) afforded [Bun4N][Ru(N)(OR)4] (R = C6F5 (1), C6F4H (2), C6Br5 (3)), whereas that with [Bun4N][Os(N)Cl4] gave [Bun4N][Os(N)(OR)3Cl] (R = C6F5 (4), C6F4H (5), C6Br5 (6)). Treatment of [Bun4N][M(N)Cl4] with Na(SC6F4H) and Na(Sxyl) (xyl = 2,6-dimethylphenyl) afforded [Bun4N][M(N)(SC6F4H)4] (M = Ru (7), Os (8)) and [Bun4N][M(N)(Sxyl)4] (M = Ru (9), Os (10)), respectively. The crystal structures of compounds 1, 6 and 9 have been determined.
Treatment of [Bun4N][Ru(N)Cl4] with Na(OR) afforded [Bun4N][Ru(N)(OR)4] (R = C6F5 (1), C6F4H (2), C6Br5 (3)), whereas that with [Bun4N][Os(N)Cl4] gave [Bun4N][Os(N)(OR)3Cl] (R = C6F5 (4), C6F4H (5), C6Br5 (6)). Treatment of [Bun4N][M(N)Cl4] with Na(SC6F4H) and Na(Sxyl) (xyl = 2,6-dimethylphenyl) afforded [Bun4N][M(N)(SC6F4H)4] (M = Ru (7), Os (8)) and [Bun4N][M(N)(Sxyl)4] (M = Ru (9), Os (10)), respectively.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 362, Issue 15, 1 December 2009, Pages 5190–5194