کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311858 | 975360 | 2005 | 5 صفحه PDF | دانلود رایگان |
A new tri-cyanometalate building block for heterometallic complexes, [PPh4]2[FeII(Tpms)(CN)3] (2) (PPh4 = tetraphenylphosphonium; Tpms = tris(pyrazolyl) methanesulfonate), has been prepared. Using it as a building block, a one-dimensional chain compound, {[FeII(Tpms)(CN)3][MnII(H2O)2( DMF)2]} · DMF (3), has been synthesized and structurally characterized. The magnetic properties of 3 correspond to a ferromagnetic chain with weak long-range superexchanged magnetic interaction between the high-spin manganese(II) ions.
A new one-dimensional chain compound, {[FeII(Tpms)(CN)3][MnII(H2O)2(DMF)2]} · DMF (Tpms = tris(pyrazolyl) methanesulfonate), has been synthesized and structurally characterized. The magnetic properties of this complex correspond to a ferromagnetic chain with weak long-range superexchanged magnetic interaction between the high-spin manganese(II) ions.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 358, Issue 13, 1 September 2005, Pages 4057–4061