Thioarsenate anions acting as ligands: Solvothermal syntheses, crystal structures and characterizations of transition metal complexes of thioarsenate and polyethyleneamine ligands

New transition metal complexes with thioarsenate ligands were prepared by solvothermal reaction in polyamines, and the first examples of TM-AsS3 complexes with polyethyleneamine coligands were obtained.191