A 3D heterometallic framework containing Co–O–Li linkages: Hydrothermal synthesis, crystal structure and magnetic property

• A 3D heterometallic framework containing Co–O–Li linkages has been isolated.
• 1 Represents a 3D hybrid magnetic rigid framework.
• Such a chain with the arrangement of Co–O–Li linkages based on carboxylic acid has been first reported.

Using dioxyacetic acid (H2oda), CoCl2·6H2O and LiOH, a three-dimensional (3D) heterometallic complex [CoLi2(oda)2]n (1) containing 1D Co–O–Li chains has been isolated under hydrothermal conditions. 1 represents a 3D hybrid magnetic rigid framework. To the best of our knowledge, such a chain with the arrangement of Co–O–Li linkages based on carboxylic acid has been first reported. Further analysis reveals that cis-conformation of dioxyacetic acid greatly favor chelate coordination of lithium(I) centers. Magnetic measurements indicate that in the low temperature, complex 1 shows weak ferromagnetic interaction, indicative of spin-canting behavior.

Using oxydiacetate acid (H2oda), CoCl2·6H2O and LiOH, a three-dimensional (3D) heterometallic complex [CoLi(oda)2]n (1) containing 1D Co–O–Li chains has been isolated under hydrothermal conditions. 1 represents a 3D hybrid magnetic rigid framework. To the best of our knowledge, such a chain with the arrangement of Co–O–Li linkages based on carboxylic acid is the first reported. Further analysis reveals that cis-conformation of oxydiacetate acid greatly favor chelate coordination of lithium(I) centers. Magnetic measurements indicate that in the low temperature, complex 1 shows weak ferromagnetic interaction, indicative of spin-canting behavior.Figure optionsDownload as PowerPoint slide