کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312511 | 1499204 | 2012 | 5 صفحه PDF | دانلود رایگان |
The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]·2CH3CN (1·2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV–Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar.
The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper (II) complex [Cu2Cl4L2]·2CH3CN (1·2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV–Vis and EPR spectroscopy.Figure optionsDownload as PowerPoint slideHighlights
► [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole].
► Copper(II) complex.
► X-ray diffraction.
► EPR spectroscopy.
Journal: Inorganica Chimica Acta - Volume 383, 30 March 2012, Pages 327–331