کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312632 | 975472 | 2010 | 5 صفحه PDF | دانلود رایگان |
Five novel complexes with two pyridine substituted benzotriazole ligands, 1-(2-pyridyl)benzotriazole (L1) and 1-(4-pyridyl)benzotriazole (L2), [Zn(L1)2Cl2] (1), [{Zn(L1)2Cl2}·(L1)2] (2), [Zn(L2)2Cl2] (3), [{Zn(L2)(H2O)3(μ2-SO4)}·H2O] (4), and [{Cd(L2)(H2O)3(μ2-SO4)}·H2O] (5) were synthesized. The details of the structures were characterized by X-ray single crystal analysis, revealing that these complexes were assembled together via supramolecular interaction, such as, hydrogen bonding and π–π interactions. The influence of organic ligands, anions and reaction conditions in the formation of the complexes were investigated.
Five novel complexes with triazolate ligands, 1-(2-pyridyl)benzotriazole (L1) and 1-(4-pyridyl)benzotriazole (L2), were synthesized. The structures were characterized by X-ray single crystal analysis, revealing that these complexes were assembled together via supramolecular interaction. The influence of organic ligands, anions and reaction conditions in the formation of the complexes were investigated.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 363, Issue 6, 5 April 2010, Pages 1320–1324