Synthesis, structure and magnetic properties of a new family of chiral metal(II) citramalates

A new series of chiral carboxylate-bridged complexes of Mn(II), Co(II), and Ni(II) has been synthesized by reaction of M(II) salts with (S)-2-hydroxy-2-methyl-butanedioic acid ((S)-citramalic acid) under solvothermal conditions. The Mn(II) compound 1 is obtained as a crystalline powder, whereas the Co(II) and Ni(II) compounds (2 and 3 respectively) are obtained as single crystals. All the compounds crystallize in orthorhombic chiral space group P212121. Compounds 2 and 3 are isostructural, and their structure consists in helicoïdal chains of M(II) centres linked by carboxylate bridges. The magnetic data indicate a rather weak coupling interaction between paramagnetic centres. The Mn(II) compound 1 exhibits antiferromagnetic ordering at TN = 2.64 K. The Co(II) and Ni(II) compounds show ferromagnetic interactions within the chains. For 3, the chains couple antiferromagnetically, which leads to a metamagnetic behaviour with TN = 1.69 K.

Chiral carboxylate-bridged complexes of transition metals, M(II) = Mn(II), Co(II) and Ni(II) were synthesized by the reaction of M(II) salts with (S)-citramalic acid ((S)-2-hydroxy-2-methyl-butanedioic acid) under solvothermal conditions. These complexes have been fully characterized structurally and magnetically. The magnetic data show a rather weak coupling interaction between paramagnetic centres. Circular dichroism measurements indicate a transfer of chirality from the citramalate to the magnetic centre.Figure optionsDownload as PowerPoint slide