کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312896 | 975512 | 2006 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Syntheses and characterization of novel sterically demanding amido ligand derivatives and their alkali metal ion complexes, crystal structures of [SiH2Mes2], [NH(SiHMes2)2] and [Na{N(SiHMes2)2}(OEt2)] Syntheses and characterization of novel sterically demanding amido ligand derivatives and their alkali metal ion complexes, crystal structures of [SiH2Mes2], [NH(SiHMes2)2] and [Na{N(SiHMes2)2}(OEt2)]](/preview/png/1312896.png)
Three bulky silanes, [SiH2Mes2] (1), [SiHMeMes2] (2), SiHMes3 (3), two novel amines, [NH(SiHMes2)2] (4), NH2(SiMeMes2) (5), and three novel alkali metal ion complexes, [Na{N(SiHMes2)2}(OEt2)] (6), Li{N(SiHMes2)2} (7), K{N(SiHMes2)2} (8), have been synthesized and characterized by multinuclear NMR and mass spectroscopy. The structures of compounds 1, 4 and 6 have been determined by X-ray crystallography. The spectroscopy and structural results are discussed.
Three bulky silanes, [SiH2Mes2], [SiHMeMes2], SiHMes3, two novel amines, [NH(SiHMes2)2], NH2(SiMeMes2), and three novel alkali metal ion complexes, [Na{N(SiHMes2)2}(OEt2)], Li{N(SiHMes2)2}, K{N(SiHMes2)2}, have been synthesized and characterized. The spectroscopy and structural results are discussed.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 359, Issue 12, 1 September 2006, Pages 3815–3823