Structural characterizations of some adducts of silver(I) nitrate and perchlorate with some cyclic di- (or tri-) ene organic ligands

Adducts of silver(I) nitrate and perchlorate with assorted organic poly-ene ligands are reported, all being polymeric in form (with exception of the mononuclear AgClO4:cod (1:2)), with chains comprised of alternating silver and nitrate/perchlorate components substituted or linked by unsaturated donors which complete the coordination spheres of the silver atoms.