کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1313100 | 975527 | 2006 | 6 صفحه PDF | دانلود رایگان |
Two trinuclear Pd(II) nitrosyl carboxylate complexes Pd3(NO)2(μ-OCOCX3)4(η2-ArH)2 (X = F, ArH = toluene, 3a; X = Cl, ArH = benzene, 3b) have been prepared and structurally characterized. These display a linear Pd3 array capped by terminal bent NO ligands and η2-coordinated molecules of aromatic molecules. Solution IR and NMR measurements indicate that the solid state structure of 3a is partially maintained in solution, while 3b loses benzene when dissolved in dichloromethane.
Two trinuclear Pd(II) nitrosyl carboxylate complexes Pd3(NO)2(μ-OCOCX3)4(η2-ArH)2 (X = F, ArH = toluene, 3a; X = Cl, ArH = benzene, 3b) have been prepared and structurally characterized, and their solution behavior has been studied by IR and NMR spectroscopy.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 359, Issue 5, 20 March 2006, Pages 1613–1618