کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1316739 976477 2007 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solution studies of some new oxamides – Co-ordination behaviour towards Cu(II) ions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Solution studies of some new oxamides – Co-ordination behaviour towards Cu(II) ions
چکیده انگلیسی

The co-ordination chemistry of some new oxamides towards Cu(II) ions was studied using various techniques: potentiometry, voltammetry, spectroscopy (UV–Vis, CD and EPR) and ESI–MS spectrometry. All tested compounds chelate the copper(II) ions with formation of 1:1 and 1:2 (metal-to-ligand ratio) complexes. The Cu(II) ions are bound by 1N, 2N or 3N nitrogen donor systems. Additionally, an unusual co-ordination to amide N-atoms without additional anchoring site is suggested. The 14N hyperfine splitting observed for the system ox6–Cu(II) above pH 10 clearly indicates the involvement of at least three N donor atoms in the copper ion binding. Moreover, the surrounding by three amide-N and one carbonyl-O stabilizes the high oxidation state of copper(III), although such complexes are very unstable in solution.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Inorganic Biochemistry - Volume 101, Issue 10, October 2007, Pages 1505–1516
نویسندگان
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