کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1321066 | 1499868 | 2014 | 7 صفحه PDF | دانلود رایگان |
• Four novel cationic iron(II) isonitrile complexes synthesized.
• Quantum chemical calculations on eight cationic iron(II) isonitrile complexes.
• Correlations between a series of calculated data and the Hammett parameter σp.
• No correlation with the NC-stretching frequency.
[CpFe(CO)2(THF)]+BF4− undergoes exchange of the labile THF ligand against isonitriles resulting in a shift of the NC-stretching vibration to higher energies compared to the free isonitriles. Quantum chemical calculations show that this shift is not a real indicator for the electronic character and thus the electronic influence of the substituents at the para-functionalized phenylisonitriles. In contrast, other calculated parameters such as reactions enthalpies, Fe–C distances, charges and CO-stretching frequencies clearly correlate with the Hammett constant σp.
The energy of the NC-stretching vibration of phenylisonitriles is not indicative for the substituents' influence at the phenyl ring.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 774, 15 December 2014, Pages 12–18