کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1321539 | 1499894 | 2013 | 4 صفحه PDF | دانلود رایگان |
• Highly active Pd nanoclusters catalyst in Migita–Kosugi–Stille coupling reaction.
• A practical cross-coupling catalyst system with high TONs (3.5 × 104).
• A practical cross-coupling catalyst system that do not need the use of an inert gas.
N,N-Dimethylformamide-stabilized palladium nanoclusters showed high catalytic activity for Migita–Kosugi–Stille cross-coupling reactions. The present cross-coupling reaction proceeded efficiently using very small Pd catalyst loadings under ligandless, and even an open air, conditions. The reactions proceeded smoothly in good yields and with high turnover numbers of up to 3.5 × 104.
N,N-Dimethylformamide-stabilized palladium nanoclusters showed high catalytic activity for Migita–Kosugi–Stille cross-coupling reactions. The present cross-coupling reaction proceeded efficiently using very small Pd catalyst loadings under ligandless, and even an open air, conditions. The reactions proceeded smoothly in good yields and with high turnover numbers of up to 3.5 × 104.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volumes 745–746, 15 November 2013, Pages 258–261