کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1321847 | 1499905 | 2013 | 4 صفحه PDF | دانلود رایگان |
We herein report the first successful synthesis of 1-thioisocyanato-1,7-dicarba-closo-dodecarborane, which afforded novel lipophilic thiourea analogs by reacting with weak and bulky nucleophilic amines including 1-adamantylamine, and m-carboranylamine, aniline, and 2-aminopyridine. Newly synthesized thiourea analogs were fully characterized by NMR, ESI-MS, and FTIR.
Efficient strategy to synthesize new and novel sterically-hindered 1,7-dicarba-closo-dodecaborane thiourea analogs was developed by reacting by reacting1-thioisocyanato-1,7-dicarba-closo-dodecarborane with bulky and weak amine nucleophiles.Figure optionsDownload as PowerPoint slideHighlights
► First synthesis of 1-thioisocyanato-1,7-dicarba-closo-dodecarborane.
► Reaction of m-carboranyl isothiocyanate with weak and bulky amines.
► Comprehensive characterization of novel thiourea analogs by NMR, ESI-MS and FT-IR.
Journal: Journal of Organometallic Chemistry - Volume 733, 1 June 2013, Pages 49–52