کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322018 1499916 2012 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Alkynylboron compounds in organic synthesis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Alkynylboron compounds in organic synthesis
چکیده انگلیسی

Alkynylboron compounds, consisting of alkynyl and boron moieties, can be categorized according to the substituents on the boron atom, such as alkynylboranes, -boronates, and -borates. In this review, the synthesis and reactions of alkynylboron compounds are systematically introduced. Alkynylpinacolatoboranes and alkynyltrifluoroborates are the most widely utilized classes in organic reactions, owing to their stability and ease of handling. Other alkynylboron compounds have also been developed as convenient substrates for various organic reactions. Thanks to the dedication of many chemists in this field, great advances of facile synthesis and wide utilization of alkynylboron compounds have been made with these versatile building blocks for diverse structures in organic synthesis.

A series of alkynylboron compounds, consisting of alkynyl and boron moieties, have been synthesized that have helped to elucidate the various organic reactions. The understanding of a historical overview of alkynylboron compounds which contributed to the unique reactions, affording the versatile building blocks for diverse structures.Figure optionsDownload as PowerPoint slideHighlights
► Alkynylboron compounds as useful substrates in organic synthesis.
► Cycloaddition reactions and their mechanistic insights.
► Regio- and stereoselective synthesis of multi-substituted olefins.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volumes 721–722, 15 December 2012, Pages 3–16
نویسندگان
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