Organic–inorganic nanotube hybrids: Organosilica-nanotubes containing ethane, ethylene and acetylene groups

The synthesis and characterization of novel organic–inorganic hybrid nanotubes containing silica and ethane (EtSNT), ethylene (ESNT) and acetylene (ASNT) units are presented. The unsaturated hydrocarbon linkers can be applied for a chemical functionalization of the surface of the silica nanotubes, e.g. for the grafting of organic/inorganic or organometallic molecules. These new materials are synthesized via a template method using V3O7·H2O fibers and characterized by solid state MAS-NMR, FT-IR, TEM and elementary analysis. In a first approach to potential applications of these materials, the grafting of glycine on ESNT by treatment of the CC groups with Br2 and subsequent substitution by glycine is investigated. The resulting material is characterized by solid state MAS-NMR, FT-IR, XRD, TGA, BET adsorption measurements and elementary analysis.

Novel organic–inorganic hybrid nanotubes containing silica and ethane (EtSNT), ethylene (ESNT) and acetylene (ASNT) have been synthesized via a template method using V3O7·H2O fibers. These new materials have been characterized by solid-state MAS-NMR, FT-IR, TEM and elementary analysis. The grafting of glycine on ESNT by treatment of the CC groups with Br2 and subsequent substitution by glycine is investigated.Figure optionsDownload as PowerPoint slideHighlights
► Preparation of organic-inorganic hybrid nanotubes via template synthesis.
► Nanotubes contain alternating silica and ethane, ethylene and acetylene units.
► Nanotube ends are uncapped.
► Length and diameter vary with the quality of the template.
► Immobilization of glycine on modified ethylenesilica-nanotubes.