کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1322793 | 977247 | 2009 | 5 صفحه PDF | دانلود رایگان |
A new nano-sized Pb(II) one-dimensional coordination polymer with η2 Pb–C interactions, [Pb2(μ3-ba)2(μ2-ba)2]n (1) [ba− = benzylacetylacetonate] has been synthesized and characterized by SEM, X-ray powder diffraction, IR spectroscopy and elemental analyses. Single-crystal X-ray diffraction shows the coordination number of Pb(II) ions is seven and the lead atoms have hemidirected coordination sphere containing involving Pb⋯C interactions, C2O7Pb. PbO nanoparticles were obtained by calcinations of the nano-sized compound 1 at 600 °C.
Nano-structures of a new Pb(II) one-dimensional polymer with η2 Pb–C interactions, [Pb2(μ3-ba)2(μ2-ba)2]n (1) [ba− = benzylacetylacetonate] were synthesized by both thermal gradient and sonochemical methods. The new nano-structure was characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 22, 15 October 2009, Pages 3565–3569