کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1322995 | 1499842 | 2016 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Structural diversity of phenoxy functionalized triazol-5-ylidene palladium(II) complexes and their application in C–N bond formation Structural diversity of phenoxy functionalized triazol-5-ylidene palladium(II) complexes and their application in C–N bond formation](/preview/png/1322995.png)
• A new series of mono-, bis-, and heteroleptic palladium-MIC complexes is reported.
• All metal complex syntheses are performed in one step and under air.
• PEPPSI complexes catalyzed the C–N bond formation between aryl halides and several amines.
The preparation and isolation of a variety of mono-, bis-, and heteroleptic mesoionic triazol-5-ylidene palladium(II) complexes is reported. Treatment of phenoxy functionalized triazolium salts [Bn-MIC(H)]+I− (1) and [Mes-MIC(H)]+I− (2) with half equivalent of palladium acetate, produced complexes 3 and 4 with a general structure of [(MIC)2Pd(I)2] as isomeric cis/trans mixtures. When the reaction of palladium acetate and the cationic precursors was carried out with equimolar amounts in presence of sodium iodide, the μ2-I2 bridged complexes 5 and 6 of the type [(MIC)PdI2]2 were obtained as unique products. Additionally, the preparation of the heteroleptic PEPPSI-type complexes ([Py(PdI2)MIC]) 7 and 8 was readily achieved by the thermal treatment of the triazolium precursors with PdCl2, K2CO3, and sodium iodide in pyridine. All complexes have been fully characterized by 1H and 13C NMR, FT-IR, elemental analysis, and in the case of 2, 3trans, 6, and 7 single crystal X-ray diffraction. Preliminary catalytic results with the palladium series established the enhanced performance of PEPPSI complexes 7 and 8 in the Buchwald-Hartwing catalyzed formation of C–N bonds between aryl halides and primary/secondary amines under mild reaction conditions.
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Journal: Journal of Organometallic Chemistry - Volume 803, 1 February 2016, Pages 142–149