کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322996 1499842 2016 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Palladium-catalyzed carbonylative C–H activation of arenes with norbornene as the coupling partner
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Palladium-catalyzed carbonylative C–H activation of arenes with norbornene as the coupling partner
چکیده انگلیسی


• The first study on carbonylative C–H activation and cyclization with alkene.
• Applying molybdenum hexacarbonyl (Mo(CO)6) or paraformaldehyde as the solid CO sources.
• Carbonylative synthesis of heterocycles.

An interesting transformation on palladium-catalyzed carbonylative C–H activation of arenes with norbornene as the coupling partner has been developed. By applying molybdenum hexacarbonyl (Mo(CO)6) or paraformaldehyde as the solid CO sources, various 5-(pyridin-2-yl)-hexahydro-7,10-methanophenanthridin-6(5H)-ones were produced in moderate yields in the presence of palladium catalyst. Interestingly, when DDQ was applied the oxidant, the product was over oxidized to the corresponding 5-(pyridin-2-yl)-tetrahydro-7,10-methanophenanthridin-6(5H)-one.

An interesting palladium-catalyzed carbonylative C–H activation of arenes with norbornene as the coupling partner has been developed. By applying Mo(CO)6 or paraformaldehyde as the solid CO sources, moderate yields of the desired products can be obtained.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 803, 1 February 2016, Pages 9–12
نویسندگان
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