کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323243 977275 2008 15 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Facile activation of hydrogen by unsaturated platinum-osmium carbonyl cluster complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Facile activation of hydrogen by unsaturated platinum-osmium carbonyl cluster complexes
چکیده انگلیسی
The electronically unsaturated cluster complex Os3Pt2(CO)10(PBut3)2 (10) was obtained from the reaction of Os3(CO)10(NCMe)2 with Pt(PBut3)2. Compound 10 reacts with hydrogen at 0 °C to yield the di- and tetra-hydrido compounds Os3Pt2(CO)10(PBut3)2(μ-H)2 (11) and Os3Pt2(CO)10(PBut3)2(μ-H)4 (12) by sequentially cleaving a Pt-Os bond with each addition of hydrogen. The hydrogen was eliminated from 11 by purging their solutions with nitrogen.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 5, 1 March 2008, Pages 819-833
نویسندگان
, , ,