کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323317 1499929 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of nonamethylrhodocenium and iridocenium hexafluorophosphate salts
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of nonamethylrhodocenium and iridocenium hexafluorophosphate salts
چکیده انگلیسی

Nonamethylrhodocenium hexafluorophosphate and nonamethyliridocenium hexafluorophosphate have been obtained by reaction of lithium tetramethylcyclopentadienide with the appropriate dichloropentamethylcyclopentadienyl metal dimers, followed by treatment with ammonium hexafluorophosphate. The crystal structures of nonamethyliridocenium hexafluorophosphate and 1,2,3,4,5-pentamethylrhodocenium hexafluorophosphate have been determined and compared to related structures. The electrochemical properties of the new cations are compared to those of other group 9 metallocenium species.

Nonamethylrhodocenium and nonamethyliridocenium hexafluorophosphate salts have been synthesized and characterized. The crystal structures of nonamethyliridocenium hexafluorophosphate and 1,2,3,4,5-pentamethylrhodocenium hexafluorophosphate have been determined and compared to related structures. The electrochemical properties of the new cations are compared to those of other group 9 metallocenium species.Figure optionsDownload as PowerPoint slideHighlights
► Synthesis of nonamethylrhodocenium and iridocenium hexafluorophosphates.
► Crystal structures of Ir example and of RhCp*Cp.PF6.
► Electrochemical comparison with other group 9 metallocenium cations.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volumes 706–707, 1 June 2012, Pages 140–143
نویسندگان
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