کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323381 1499848 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Gold-catalyzed cycloisomerization of [3]-cumulenols
ترجمه فارسی عنوان
سیکلوئیزومریز شدن کاتالیزورهای طلایی [3] -کولینول ها
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• First gold-catalyzed cycloisomerization of cumulenols.
• Reaction outcome dependent from the gold oxidation state.
• A new access to trisubstituted furan derivatives.
• Gold(I) π-activation of the cumulene moeity.

The gold-catalyzed cycloisomerization of tetrasubstituted [3]-cumulenols has been investigated. Overall, two main pathways are followed. In the presence of gold(III) catalysts, a dehydration process prevails giving diastereomerically pure dienynes while gold(I) catalysts favor the cycloisomerization to provide trisubstituted furan derivatives.

The gold-catalyzed cycloisomerization of tetrasubstituted [3]-cumulenols has been investigated. Overall, two main pathways are followed. In the presence of gold(III) catalysts, a dehydration process prevails giving diastereomerically pure dienynes while gold(I) catalysts favor the cycloisomerization to provide trisubstituted furan derivatives.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 795, 15 October 2015, Pages 53–57
نویسندگان
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