کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1323768 1499950 2006 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Total synthesis of (±)-erythrocarine using dienyne metathesis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Total synthesis of (±)-erythrocarine using dienyne metathesis
چکیده انگلیسی

Total Synthesis of (±)-erythrocarine was achieved using ruthenium-catalyzed dienyne metathesis as a key step. A tetrahydroisoquinoline skeleton having tetrasubstituted carbon center was constructed using our method, that is, carbon dioxide and an alkyl group were introduced onto an alkyne having a heteroatom in a tether using the nickel complex to produce α,β-unsaturated carboxylic acid and then isoquinoline skeleton was constructed by Michael reaction of the tethered nitrogen to the resultant α,β-unsaturated ester.

Total Synthesis of (±)-erythrocarine was achieved using ruthenium-catalyzed dienyne metathesis as a key step.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issues 24–25, 1 December 2006, Pages 5466–5475
نویسندگان
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