کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1324194 | 977327 | 2010 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and complexation of dichalcogenoethers with cyclopropyl backbones, (CH2EMe)2 (E = Se or Te) Synthesis and complexation of dichalcogenoethers with cyclopropyl backbones, (CH2EMe)2 (E = Se or Te)](/preview/png/1324194.png)
The reaction of LiTeMe with C(CH2Br)4 in thf gives (CH2TeMe)2 irrespective of the ratio of reactants, in contrast to the reaction with LiSeMe, which gives either C(CH2SeMe)4 or (CH2SeMe)2 depending upon the reaction conditions. The synthesis and properties of [(CH2TeMe2)2]I2, (CH2TeMeI2)2, [Mn(CO)3Cl{(CH2EMe)2}] (E = Se or Te) and [MCl(η6-p-cymene){(CH2EMe)2}]PF6 (M = Ru or Os) are described. X-ray crystal structures are reported for [(CH2TeMe2)2]I2, [Mn(CO)3Cl{(CH2TeMe)2}], [MCl(η6-p-cymene){(CH2TeMe)2}]PF6 (M = Ru, E = Se or Te and M = Os, E = Se). The effect of the cyclopropyl ring in the ligand backbone is to open up the C–C–C angle within the chelate ring, compared with trimethylene linked analogues. Selenium–carbon bond fission occurs on attempted quaternisation of o-C6H4(CH2SeMe)2 or (CH2SeMe)2 with MeI yielding [Me3Se]I.
The synthesis of (CH2TeMe)2, some organotellurium(IV) derivatives and complexes [Mn(CO)3Cl{(CH2EMe)2}] (E = Se or Te) and [MCl(η6-p-cymene){(CH2EMe)2}]PF6 (M = Ru or Os) are described.Figure optionsDownload as PowerPoint slideFigure optionsDownload as PowerPoint slideFigure optionsDownload as PowerPoint slideFigure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 9, 1 May 2010, Pages 1346–1352