کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1324214 977328 2011 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and electrochemical properties of crown ether functionalized coumarin substituted cobalt and copper phthalocyanines
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and electrochemical properties of crown ether functionalized coumarin substituted cobalt and copper phthalocyanines
چکیده انگلیسی

The synthesis of novel 6,7-[15-crown-5]-3-[p-(3,4-dicyanophenoxy)phenyl]coumarin (1)/6,7-[15-crown-5]-3-[p-(2,3-dicyanophenoxy)phenyl]coumarin (2) and their peripherally/non-peripherally cobalt and copper phthalocyanine complexes (3–6) have been prepared and characterized by elementel analysis, 1H-NMR, MALDI-TOF, FT-IR and UV–Vis spectral data. Fluorescence intensity changes of compound 1 and 2 have been determined by addition of Na+ or K+ ions at 25 °C in THF. The effect of substitution type on the redox and aggregation behaviour of the compounds was investigated by voltammetry and in situ spectroelectrochemistry.

Figure optionsDownload as PowerPoint slideHighlights
► Crown ether.
► Cobalt and copper phthalocyanines.
► Spectroelectrochemical measurements.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 24, 1 December 2011, Pages 3873–3881
نویسندگان
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