کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324214 | 977328 | 2011 | 9 صفحه PDF | دانلود رایگان |

The synthesis of novel 6,7-[15-crown-5]-3-[p-(3,4-dicyanophenoxy)phenyl]coumarin (1)/6,7-[15-crown-5]-3-[p-(2,3-dicyanophenoxy)phenyl]coumarin (2) and their peripherally/non-peripherally cobalt and copper phthalocyanine complexes (3–6) have been prepared and characterized by elementel analysis, 1H-NMR, MALDI-TOF, FT-IR and UV–Vis spectral data. Fluorescence intensity changes of compound 1 and 2 have been determined by addition of Na+ or K+ ions at 25 °C in THF. The effect of substitution type on the redox and aggregation behaviour of the compounds was investigated by voltammetry and in situ spectroelectrochemistry.
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► Crown ether.
► Cobalt and copper phthalocyanines.
► Spectroelectrochemical measurements.
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 24, 1 December 2011, Pages 3873–3881