کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1324483 977342 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones
چکیده انگلیسی

A new class of hemilabile unsymmetrical 2-(1-arylimino)-6-(pyzazol-1-yl)pyridine ligands and their ruthenium(II) and nickel(II) NNN complexes were synthesized. The Ru(II) complex catalysts have been fully characterized and exhibited good to excellent catalytic activity in the transfer hydrogenation (TH) of ketones in refluxing 2-propanol. These results have demonstrated rare examples of active ruthenium(II) NNN complex catalysts that do not feature a N–H functionality for TH of ketones.

Ruthenium(II) complexes bearing a unsymmetrical 2-(1-arylimino)-6-(pyzazol-1-yl)pyridine ligand exhibited good to excellent catalytic activity in the transfer hydrogenation of ketones in refluxing 2-propanol.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 19, 1 September 2009, Pages 3068–3075
نویسندگان
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