کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324752 | 1499921 | 2012 | 5 صفحه PDF | دانلود رایگان |
The reaction of [Ru3(CO)12] with 1,4-benzoquinone, in a hydrogen atmosphere led to the formation of a product with the formula [(μ-H)Ru3(CO)10(μ2-O–C6H4OH)] which crystallizes with two molecules of free hydroquinone in the asymmetric unit with which it forms an arrangement of hydrogen bridges leading to a layered structure of trinuclear metallic and hydroquinone fragments. Electrochemical studies showed that electrode inhibition is obtained by cycling of the oxidation process of this compound.
The structure of compound [(μ-H)Ru3(CO)10(μ2-O–C6H4OH)] shows it to co-crystallize with two molecules of free hydroquinone forming a layered structure of trinuclear metallic and hydroquinone fragments.Figure optionsDownload as PowerPoint slideHighlights
► The reaction of [Ru3(CO)12] with benzoquinone and hydrogen was carried out.
► The crystal structure shows the presence of intramolecular interactions.
► Electrochemical measurements of the product indicate electrode inhibition occurs.
Journal: Journal of Organometallic Chemistry - Volume 716, 1 October 2012, Pages 289–293